The bivariate chromatic polynomial $\chi_G(x,y)$ of a graph $G = (V, E)$, introduced by Dohmen-Pönitz-Tittmann (2003), counts all $x$-colorings of $G$ such that adjacent vertices get different colors if they are $\le y$. We extend this notion to mixed graphs, which have both directed and undirected edges. Our main result is a decomposition formula which expresses $\chi_G(x,y)$ as a sum of bivariate order polynomials (Beck-Farahmand-Karunaratne-Zuniga Ruiz 2020), and a combinatorial reciprocity theorem for $\chi_G(x,y)$.